Ethylene adsorption on Pd( 111 ) studied using infrared reflection–absorption spectroscopy

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Ethylene adsorption on Pd(111) studied using infrared reflection–absorption spectroscopy

The adsorption of ethylene has been studied on clean and hydrogen-covered Pd(1 1 1) using reflection–absorption infrared spectroscopy and molecular beam methods. Using a correlation diagram, in which vibrational frequencies are plotted versus a rp parameter proposed by Stuve and Madix, shows that ethylene is substantially rehybridized on Pd(1 1 1) having a rp parameter intermediate between thos...

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ژورنال

عنوان ژورنال: Surface Science

سال: 2002

ISSN: 0039-6028

DOI: 10.1016/s0039-6028(02)01498-x